Journal of Organometallic Chemistry

The haloboration of n-hexyne-1

JR Blackborow

文献索引：Blackborow,J.R. Journal of Organometallic Chemistry, 1977 , vol. 128, p. 161 - 166

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被引用次数: 23

摘要

Abstract The assignment of configurations to isomers of 2-halo-2-phenylvinylboranes and 1- halo-1-phenyl-2-deuteroethylenes described in a previous paper has been revised. The mechanism of haloboration of n-hexyne-1 is discussed in the light of the geometrical isomer ratios of 2-halohex-1-ene-1-ylboranes obtained as products.