Synthesis of Group 9 Metal??Olefin Complexes with Identical Ligand Frameworks and Comparison of their Catalytic Activity in [2+ 2+ 2] Cycloaddition and other …
…, R Jackstell, H Jiao, A Spannenberg…
文献索引：Weding, Nico; Jackstell, Ralf; Jiao, Haijun; Spannenberg, Anke; Hapke, Marko Advanced Synthesis and Catalysis, 2011 , vol. 353, # 18 p. 3423 - 3433
Abstract The preparation and catalytic evaluation of the three group 9 (cyclopentadienyl) metal (trimethylvinylsilane) complexes of the type C 5 H 5 M (H 2 C [DOUBLE BOND] CHSiMe 3) 2 (M= cobalt, rhodium and iridium) are reported. The complexes were investigated in [2+ 2+ 2] cycloaddition as well as in hydrogenation, hydroformylation and hydroboration reactions. Despite the identical organic frameworks and structural ...
