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举例 :可输入Filippa Pettersson 或者 Cancer Res. 75(6) , 1102-12, (2015) 或者10.1002/anie.201600521

Tetrahedron

Cyclisatioh de diarylalcanes en milieu superacide: synthese de cetones tricycliques a methyle angulaire et mecanisme de leur isomerisation

C Berrier, JC Jacquesy, JP Gessom, A Renoux

文献索引：Berrier, C.; Jacquesy, J. C.; Gesson, J. P.; Renoux, A. Tetrahedron, 1984 , vol. 40, # 11 p. 1983 - 1994

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被引用次数: 4

摘要

Cyclisation of readily available diary1-1, 2 ethanes 1→ 4 proceeds in SbF5,-HF at 0° C to yield tricyclic phenanthrenones 5, 6, 7 and 11 bearing an angular methyl group. This process implies the electrophilic attack of the more basic aromatic ring, reacting through its diprotonated form (on the oxygen and the meta carbon atom) on the second aromatic ring. Isomerization of these primary products may be observed to give ketones 8, 9, 10 from 3 ...

间甲氧基氯苄结构式

间甲氧基氯苄

~%

3-甲氧基苄基氯化镁结构式

3-甲氧基苄基氯化镁

4-methoxy-1-methyl-2-(2-phenylethyl)benzene结构式

4-methoxy-1-met...

~70%

4a-Methyl-4,4a,9,10-tetrahydrophenanthrene-2(3H)-one结构式

4a-Methyl-4,4a,...

4-甲氧基-N,N-二甲基-苯甲胺结构式

4-甲氧基-N,N-二甲基-苯甲胺

~%

4a-Methyl-4,4a,9,10-tetrahydrophenanthrene-2(3H)-one结构式

4a-Methyl-4,4a,...

4-甲氧基苯甲醛; 对甲氧基苯甲醛; 大茴香醛结构式

4-甲氧基苯甲醛; 对甲氧基苯...

~%

4a-Methyl-4,4a,9,10-tetrahydrophenanthrene-2(3H)-one结构式

4a-Methyl-4,4a,...

5-甲氧基-2-甲基苯甲醛结构式

5-甲氧基-2-甲基苯甲醛

~%

4a-Methyl-4,4a,9,10-tetrahydrophenanthrene-2(3H)-one结构式

4a-Methyl-4,4a,...

(5-甲氧基-2-甲基苯基)甲醇结构式

(5-甲氧基-2-甲基苯基)甲醇

~%

4a-Methyl-4,4a,9,10-tetrahydrophenanthrene-2(3H)-one结构式

4a-Methyl-4,4a,...

1-(5-methoxy-2-methyl-phenyl)-N,N-dimethyl-methanamine结构式

1-(5-methoxy-2-...

~%

4a-Methyl-4,4a,9,10-tetrahydrophenanthrene-2(3H)-one结构式

4a-Methyl-4,4a,...

(4-methoxyphenyl)methyl-trimethyl-azanium结构式

(4-methoxypheny...

~%

4a-Methyl-4,4a,9,10-tetrahydrophenanthrene-2(3H)-one结构式

4a-Methyl-4,4a,...

4-甲氧基-N,N-二甲基-苯甲胺结构式

4-甲氧基-N,N-二甲基-苯甲胺

碘甲烷结构式

~%

(4-methoxyphenyl)methyl-trimethyl-azanium结构式

(4-methoxypheny...

4-甲氧基苯甲醛; 对甲氧基苯甲醛; 大茴香醛结构式

4-甲氧基苯甲醛; 对甲氧基苯...

~%

(4-methoxyphenyl)methyl-trimethyl-azanium结构式

(4-methoxypheny...

4-甲氧基-N,N-二甲基-苯甲胺结构式

4-甲氧基-N,N-二甲基-苯甲胺

~%

4-methoxy-2-[2-(2-methoxyphenyl)ethyl]-1-methylbenzene结构式

4-methoxy-2-[2-...

4-甲氧基苯甲醛; 对甲氧基苯甲醛; 大茴香醛结构式

4-甲氧基苯甲醛; 对甲氧基苯...

~%

4-methoxy-2-[2-(2-methoxyphenyl)ethyl]-1-methylbenzene结构式

4-methoxy-2-[2-...

5-甲氧基-2-甲基苯甲醛结构式

5-甲氧基-2-甲基苯甲醛

~%

4-methoxy-2-[2-(2-methoxyphenyl)ethyl]-1-methylbenzene结构式

4-methoxy-2-[2-...

(5-甲氧基-2-甲基苯基)甲醇结构式

(5-甲氧基-2-甲基苯基)甲醇

~%

4-methoxy-2-[2-(2-methoxyphenyl)ethyl]-1-methylbenzene结构式

4-methoxy-2-[2-...

1-(5-methoxy-2-methyl-phenyl)-N,N-dimethyl-methanamine结构式

1-(5-methoxy-2-...

~%

4-methoxy-2-[2-(2-methoxyphenyl)ethyl]-1-methylbenzene结构式

4-methoxy-2-[2-...

(4-methoxyphenyl)methyl-trimethyl-azanium结构式

(4-methoxypheny...

~%

4-methoxy-2-[2-(2-methoxyphenyl)ethyl]-1-methylbenzene结构式

4-methoxy-2-[2-...

2-甲氧基苄基氯结构式

2-甲氧基苄基氯

~%

4-methoxy-2-[2-(2-methoxyphenyl)ethyl]-1-methylbenzene结构式

4-methoxy-2-[2-...

2-甲氧基苄基氯化镁结构式

2-甲氧基苄基氯化镁

~%

4-methoxy-2-[2-(2-methoxyphenyl)ethyl]-1-methylbenzene结构式

4-methoxy-2-[2-...

4-甲氧基-N,N-二甲基-苯甲胺结构式

4-甲氧基-N,N-二甲基-苯甲胺

~%

4-methoxy-2-[2-(4-methoxyphenyl)ethyl]-1-methylbenzene结构式

4-methoxy-2-[2-...

4-甲氧基苯甲醛; 对甲氧基苯甲醛; 大茴香醛结构式

4-甲氧基苯甲醛; 对甲氧基苯...

~%

4-methoxy-2-[2-(4-methoxyphenyl)ethyl]-1-methylbenzene结构式

4-methoxy-2-[2-...

5-甲氧基-2-甲基苯甲醛结构式

5-甲氧基-2-甲基苯甲醛

~%

4-methoxy-2-[2-(4-methoxyphenyl)ethyl]-1-methylbenzene结构式

4-methoxy-2-[2-...

(4-甲氧基苄基)磷酸二乙酯结构式

(4-甲氧基苄基)磷酸二乙酯

~%

4-methoxy-2-[2-(4-methoxyphenyl)ethyl]-1-methylbenzene结构式

4-methoxy-2-[2-...

(5-甲氧基-2-甲基苯基)甲醇结构式

(5-甲氧基-2-甲基苯基)甲醇

~%

4-methoxy-2-[2-(4-methoxyphenyl)ethyl]-1-methylbenzene结构式

4-methoxy-2-[2-...

1-(5-methoxy-2-methyl-phenyl)-N,N-dimethyl-methanamine结构式

1-(5-methoxy-2-...

~%

4-methoxy-2-[2-(4-methoxyphenyl)ethyl]-1-methylbenzene结构式

4-methoxy-2-[2-...

(4-methoxyphenyl)methyl-trimethyl-azanium结构式

(4-methoxypheny...

~%

4-methoxy-2-[2-(4-methoxyphenyl)ethyl]-1-methylbenzene结构式

4-methoxy-2-[2-...

4-甲氧基苄氯结构式

4-甲氧基苄氯

~%

4-methoxy-2-[2-(4-methoxyphenyl)ethyl]-1-methylbenzene结构式

4-methoxy-2-[2-...

4-甲氧基-N,N-二甲基-苯甲胺结构式

4-甲氧基-N,N-二甲基-苯甲胺

~%

4-methoxy-2-[2-(3-methoxyphenyl)ethyl]-1-methylbenzene结构式

4-methoxy-2-[2-...

4-甲氧基苯甲醛; 对甲氧基苯甲醛; 大茴香醛结构式

4-甲氧基苯甲醛; 对甲氧基苯...

~%

4-methoxy-2-[2-(3-methoxyphenyl)ethyl]-1-methylbenzene结构式

4-methoxy-2-[2-...

5-甲氧基-2-甲基苯甲醛结构式

5-甲氧基-2-甲基苯甲醛

~%

4-methoxy-2-[2-(3-methoxyphenyl)ethyl]-1-methylbenzene结构式

4-methoxy-2-[2-...

(5-甲氧基-2-甲基苯基)甲醇结构式

(5-甲氧基-2-甲基苯基)甲醇

~%

4-methoxy-2-[2-(3-methoxyphenyl)ethyl]-1-methylbenzene结构式

4-methoxy-2-[2-...

1-(5-methoxy-2-methyl-phenyl)-N,N-dimethyl-methanamine结构式

1-(5-methoxy-2-...

~%

4-methoxy-2-[2-(3-methoxyphenyl)ethyl]-1-methylbenzene结构式

4-methoxy-2-[2-...

(4-methoxyphenyl)methyl-trimethyl-azanium结构式

(4-methoxypheny...

~%

4-methoxy-2-[2-(3-methoxyphenyl)ethyl]-1-methylbenzene结构式

4-methoxy-2-[2-...

3-甲氧基苄基氯化镁结构式

3-甲氧基苄基氯化镁

~%

4-methoxy-2-[2-(3-methoxyphenyl)ethyl]-1-methylbenzene结构式

4-methoxy-2-[2-...

间甲氧基氯苄结构式

间甲氧基氯苄

~%

4-methoxy-2-[2-(3-methoxyphenyl)ethyl]-1-methylbenzene结构式

4-methoxy-2-[2-...

4-甲氧基-N,N-二甲基-苯甲胺结构式

4-甲氧基-N,N-二甲基-苯甲胺

~%

4-methoxy-1-methyl-2-(2-phenylethyl)benzene结构式

4-methoxy-1-met...

4-甲氧基苯甲醛; 对甲氧基苯甲醛; 大茴香醛结构式

4-甲氧基苯甲醛; 对甲氧基苯...

~%

4-methoxy-1-methyl-2-(2-phenylethyl)benzene结构式

4-methoxy-1-met...

5-甲氧基-2-甲基苯甲醛结构式

5-甲氧基-2-甲基苯甲醛

~%

4-methoxy-1-methyl-2-(2-phenylethyl)benzene结构式

4-methoxy-1-met...

(5-甲氧基-2-甲基苯基)甲醇结构式

(5-甲氧基-2-甲基苯基)甲醇

~%

4-methoxy-1-methyl-2-(2-phenylethyl)benzene结构式

4-methoxy-1-met...

1-(5-methoxy-2-methyl-phenyl)-N,N-dimethyl-methanamine结构式

1-(5-methoxy-2-...

~%

4-methoxy-1-methyl-2-(2-phenylethyl)benzene结构式

4-methoxy-1-met...

(4-methoxyphenyl)methyl-trimethyl-azanium结构式

(4-methoxypheny...

~%

4-methoxy-1-methyl-2-(2-phenylethyl)benzene结构式

4-methoxy-1-met...

苄基氯化镁结构式

苄基氯化镁

~%

4-methoxy-1-methyl-2-(2-phenylethyl)benzene结构式

4-methoxy-1-met...

磷酸三乙酯结构式

磷酸三乙酯

4-甲氧基苄氯结构式

4-甲氧基苄氯

~92%

(4-甲氧基苄基)磷酸二乙酯结构式

(4-甲氧基苄基)磷酸二乙酯

(4-methoxyphenyl)methyl-trimethyl-azanium结构式

(4-methoxypheny...

~%

1-(5-methoxy-2-methyl-phenyl)-N,N-dimethyl-methanamine结构式

1-(5-methoxy-2-...

4-甲氧基-N,N-二甲基-苯甲胺结构式

4-甲氧基-N,N-二甲基-苯甲胺

~%

1-(5-methoxy-2-methyl-phenyl)-N,N-dimethyl-methanamine结构式

1-(5-methoxy-2-...

4-甲氧基苯甲醛; 对甲氧基苯甲醛; 大茴香醛结构式

4-甲氧基苯甲醛; 对甲氧基苯...

~%

1-(5-methoxy-2-methyl-phenyl)-N,N-dimethyl-methanamine结构式

1-(5-methoxy-2-...