Proton magnetic resonance spectra of cubane derivatives. I. Syntheses and spectra of mono-and 1, 4-disubstituted cubanes

JT Edward, PG Farrell, GE Langford

文献索引：Edward,J.T. et al. Journal of the American Chemical Society, 1976 , vol. 98, # 11 p. 3075 - 3085

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被引用次数: 42

摘要

Abstract: The syntheses of a number of monosubstituted and 1, 4-disubstituted cubanes are described, together with the mea-surement and analysis of their 100-MHz'H NMR spectra. Typical coupling constants observed are 5.3 Hz (vicinal), 2.5 Hz (four bond), and-0.7 Hz (five bond). A simple additivity rule is described whereby chemical shifts in CDCI, can be predicted to within d~ 0.02 ppm. Both chemical shifts and coupling constants are shown to ...