Donor specificity and regioselectivity in Lipolase mediated acylations of methyl α-d-glucopyranoside by vinyl esters of phenolic acids and their analogues
M Mastihubová, V Mastihuba
文献索引：Mastihubova, Maria; Mastihuba, Vladimir Bioorganic and Medicinal Chemistry Letters, 2013 , vol. 23, # 19 p. 5389 - 5392
Abstract Methyl α-d-glucopyranoside as a model acceptor was acylated by several phenolic and non-phenolic vinyl esters using immobilised Lipolase. Donor specificity and regioselectivity of reaction were investigated. Conversion and rate of acylation by structurally varied donors indicates that the synthetic reactivity of Lipolase corresponds to the hydrolytic activity of feruloyl esterase type A. Lipolase exhibited remarkable regioselectivity for ...
