Cyanocarbon acids. Direct evidence that their ionization is not an encounter-controlled process and rationalization of the unusual solvent isotope effects
M Hojatti, AJ Kresge, WH Wang
文献索引：Hojatti, M.; Kresge, A. J.; Wang, W.-H. Journal of the American Chemical Society, 1987 , vol. 109, # 13 p. 4023 - 4028
Conclusions In this work we have demonstrated that there are clear parallels between the heterogeneous and homogeneous chemistry of phosphomolybdate heteropolyanion systems. Surface intermediates that occur during a heterogeneous redox cycle in which methanol is oxidized have been isolated and compared to their stoichiometric counterparts by direct spectroscopic means. It has been established that the crucial intermediate is a ...
