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Double Subroutine Self??Assembly; Spontaneous Generation of a Nanocyclic Dodecanuclear Cu1 Inorganic Architecture

DP Funeriu, JM Lehn, G Baum…

文献索引:Funeriu, Daniel P.; Lehn, Jean-Marie; Baum, Gerhard; Fenske, Dieter Chemistry - A European Journal, 1997 , vol. 3, # 1 p. 99 - 104

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被引用次数: 126

摘要

Abstract The newly synthesised ligand 2 combines binding components known to undergo specific and distinct self-assembly processes with Cu 1 ions. It complexes Cu 1 to form, in almost quantitative yield, a large inorganic architecture 1 made up from four ligand molecules and twelve metal ions. The structure of 1 was ascertained by X-ray radiocrystallography as well as by NMR spectroscopy and electrospray mass ...