Synthesis, spectral, and anti-microbial studies of thioiminium iodides and amine hydrochlorides

S Britto, P Renaud, M Nallu

文献索引：Britto, Sebastian; Renaud, Philippe; Nallu, Maruthai Spectrochimica Acta - Part A: Molecular and Biomolecular Spectroscopy, 2014 , vol. 120, p. 489 - 493

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摘要

Abstract To avoid the undesired deprotonation during the addition of organolithium and organomagnesium reagents to ketones, the thioiminium salts, easily prepared from lactams and amides are converted into 2, 2-disubstituted and 2-monosubstituted amines by reaction with simple nucleophiles such as organocerium and organocopper reagents. The reaction of thioiminium iodides with organocerium reagents derived by transmetalation of ...