The Addition of Silicon Hydrides to Olefinic Double Bonds. Part V. The Addition to Allyl and Methallyl Chlorides

JW Ryan, GK Menzie, JL Speier

文献索引：Ryan,J.W. et al. Journal of the American Chemical Society, 1960 , vol. 82, p. 3601 - 3604

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被引用次数: 82

摘要

The addition of four hydrides of silicon to allyl and methallyl chlorides in the presence of chloroplatinic acid was studied. The four hydrides, trichlorosilane, methyldichlorosilane, dimethylchlorosilane, and phenyldichlorosilane each formed only one adduct, either the 3- chloropropyl-or 3-chloro-2-methylpropylsilane derivatives with allyl or methallyl chloride. No isomeric adducts such as 2-chloro-1-methylethylsilane were detectable.