Dirhodium (II) Tetrakis (perfluorobutyrate)-Catalyzed 1, 4-Hydrosilylation of. ALPHA.,. BETA.-Unsaturated Carbonyl Compounds

…, M Tanaka, K Suzuki, H Nambu, S Hashimoto

文献索引：Anada, Masahiro; Tanaka, Masahiko; Suzuki, Kanami; Nambu, Hisanori; Hashimoto, Shunichi Chemical and Pharmaceutical Bulletin, 2006 , vol. 54, # 11 p. 1622 - 1623

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被引用次数: 13

摘要

The use of dirhodium (II) catalysts in the 1, 4-hydrosilylation of α, β-unsaturated ketones and aldehydes was explored. Dirhodium (II) tetrakis (perfluorobutyrate), Rh 2 (pfb) 4, proved to be the catalyst of choice for this process, providing the corresponding silyl enol ethers in high yields.