Abstract: Morpholinobenzenes with up to four N-morpholino groups have been synthesized efficiently from the corresponding bromobenzenes via palladium catalyzed multiple aryl amination reactions. Surprisingly, hexabromobenzene (1) yielded selectively 1, 2, 4, 5-(N, N, N, N)-tetra-(23) and 1, 3, 5-(N, N, N)-trimorpholinobenzene