Tetrahedron

Regioselective preparation of vinyl chlorides from 2-methylcyclohexanone

PF Hudrlik, AK Kulkarni

文献索引：Hudrlik, Paul F.; Kulkarni, Ashok K. Tetrahedron, 1985 , vol. 41, # 7 p. 1179 - 1182

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被引用次数: 6

摘要

Treatment of 2-methylcyclohexanone with PCl5, in hexane at reflux gives predominantly 2- ch1oro-3-methylcyclohexene (3). 5On the other hand, treatment with catechyl phosphorus trichloride followed by alcoholic KOH gives predominantly the isomeric viny1 chloride, 1- chloro-2-methylcyclohexene (4).