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Dioxygen binding in iron and cobalt picnic basket porphyrins

JP Collman, X Zhang, K Wong…

文献索引:Collman, James P.; Zhang, Xumu; Wong, Kelvin; Brauman, John I. Journal of the American Chemical Society, 1994 , vol. 116, # 14 p. 6245 - 6251

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被引用次数: 84

摘要

Abstract: The synthesis and characterization of a series of iron and cobalt" picnic basket" porphyrins are described. Dioxygen binding to iron and cobalt picnic basket porphyrins has been studied by lH NMR and oxygen affinity measurements. These iron and cobalt picnic basket porphyrins bind dioxygen reversibly at room temperature with high affinities. The oxygen affinity increases as the basket size decreases. This effect indicates that a ...