The Journal of organic chemistry

Modular approach for the development of supported, monofunctionalized, salen catalysts

M Holbach, M Weck

文献索引：Holbach, Michael; Weck, Marcus Journal of Organic Chemistry, 2006 , vol. 71, # 5 p. 1825 - 1836

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被引用次数: 104

摘要

We report a modular approach toward polymer-supported, metalated, salen catalysts. This strategy is based on the synthesis of monofunctionalized Mn-and Co-salen complexes attached to a norbornene monomer via a stable phenylene-acetylene linker. The resulting functionalized monomers can be polymerized in a controlled fashion using ring-opening metathesis polymerization. This polymerization method allows for the synthesis of ...