Kinetics and mechanism of hydrolysis of methylphosphonfluoridic acid

WE Bechtold, AR Dahl

文献索引：Bechtold, W. E.; Dahl, A. R. Phosphorus and Sulfur and the Related Elements, 1987 , vol. 31, p. 193 - 202

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被引用次数: 2

摘要

Abstract The acid catalyzed rate for hydrolysis of methylphosponfluoridic acid has been determined at several hydrogen ion concentrations and temperatures. The acid hydrolysis is second order (in acid and substrate). Assumed rate expressions, observed rate constants, and hydrogen ion concentrations were used to calculate the thermodynamic equilibrium constant (K a= 0.56) and rate constants for acid catalysis. The activation energy E a has ...