Tetrahedron

Addition reactions of fluoroalkanesulfonyl azides to [60] fullerene under thermal or microwave irradiation condition

R Wu, X Lu, Y Zhang, J Zhang, W Xiong, S Zhu

文献索引：Wu, Ran; Lu, Xiaoyong; Zhang, Yun; Zhang, Jianmin; Xiong, Wanting; Zhu, Shizheng Tetrahedron, 2008 , vol. 64, # 47 p. 10694 - 10698

全文：HTML全文

被引用次数: 18

摘要

The reactions of [60] fullerene with excess fluoroalkanesulfonyl azides RfSO2N3 in o- dichlorobenzene under thermal or microwave irradiation condition afforded monoadduct opened [5, 6]-bridged azafulleroids. While, similarly treatment of 2, 2, 2-trifluoroethyl azides CF3CH2N3 with C60 gave two monoadducts, ie, opened [5, 6]-bridged azafulleroids, closed [6, 6]-bridged Aziridino-fullerene, and some multi-addition product. A general mechanism ...