Asymmetric induction and configurational correlations in oxidations at sulphur. Part V. Oxidations of optically active esters of o-(methylthio) benzoic acid by achiral …

G Barbieri, V Davoli, I Moretti, F Montanari…

文献索引：Barbieri,G. et al. Journal of the Chemical Society [Section] C: Organic, 1969 , p. 731 - 735

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摘要

Oxidation of optically active esters of-(methylthio) benzoic acid with achiral peroxy-acids (perbenzoic and 2, 4, 6-trimethylperbenzoic acids) yields mixtures of the corresponding diastereomeric sulphoxides, enriched in one of the components. Hydrolysis affords optically active-methylsulphinylbenzoic acid. The absol