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Unusual macromolecular architectures: the convergent growth approach to dendritic polyesters and novel block copolymers

CJ Hawker, JMJ Frechet

文献索引:Hawker, Craig J.; Frechet, Jean M. J. Journal of the American Chemical Society, 1992 , vol. 114, # 22 p. 8405 - 8413

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被引用次数: 184

摘要

Abstract: A versatile approach to dendritic polyesters and their use in the preparation of two different types of novel macromolecular architectures represent dendritic block copolymers is described. The chemistry developed for the synthesis of dendritic polyesters involves generation growth through an esterification step using dicyclohexylcarbodiimide (DCC) and 4-(dimethylamino) pyridinium p-toluenesulfonate (DPTS) followed by activation of the ...