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Organometallics

Organic Syntheses via Transition Metal Complexes. 109.1 Transfer of Carbene Ligands from Group VI Metals to Rhodium as the Key Step of a Rhodium-Catalyzed …

I Göttker-Schnetmann, R Aumann

文献索引:Stein, Frank; Duetsch, Michael; Lackmann, Rolf; Noltemeyer, Mathias; Meijere, Armin de Angewandte Chemie, 1991 , vol. 103, # 12 p. 1669 - 1671

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摘要

... Volume: Page: ... to the formation of vinylcyclopentadienes involves the π-cyclization of metallaoctatetraenes of type D, which are accessible from (1-alkynyl)carbene complexes 1 (R 1 = cycloalkenyl) by Michael addition of ... 13. It was shown by de Meijere et al. ...