Iterative molecular assembly based on the cation-pool method. Convergent synthesis of dendritic molecules

…, K Soga, M Okajima, S Suga, J Yoshida

文献索引：Okajima, Masayuki; Soga, Kazuya; Nokami, Toshiki; Suga, Seiji; Yoshida, Jun-Ichi Organic Letters, 2006 , vol. 8, # 22 p. 5005 - 5007

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被引用次数: 43

摘要

An iterative method for molecular assembly has been developed based on the cation-pool method using (trimethylsilyl) diphenylmethane as a building block. The silyl group works as both an activating group of the benzene ring in the Friedel− Crafts type reaction and an electroauxiliary in the subsequent low temperature anodic oxidation to generate dendritic diarylcarbenium ions, which were well characterized by low-temperature NMR ...