Tetrahedron

2-aza-1, 3-dienes: Methods of synthesis and stereochemical studies

L Ghosez, P Bayard, P Nshimyumukiza, V Gouverneur…

文献索引：Ghosez, L.; Bayard, Ph.; Nshimyumukiza, P.; Gouverneur, V.; Sainte, F.; et al. Tetrahedron, 1995 , vol. 51, # 40 p. 11021 - 11042

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被引用次数: 59

摘要

2-Aza-1, 3-dienes bearing an activating trialkylsilyloxy group at C-3 have been prepared via three routes. The first route involves the silylation of N-acylimidates which are readily available from iminoether hydrochlorides and acid chlorides. According to a more general route towards these doubly activated dienes, N-trialkylsilylimidates and N-trialkylsilylimines derived from non-enolizable aldehydes were conveniently converted in a one-pot ...