Tetrahedron

Synthesis of azoxybenzene-SbCl5 complexes and their selective ortho-wallach rearrangement

J Yamamoto, Y Nishigaki, M Umezu, T Matsuura

文献索引：Yamamoto, Jiro; Nishigaki, Yukihiro; Umezu, Masahiro; Matsuura, Teruo Tetrahedron, 1980 , vol. 36, p. 3177 - 3180

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被引用次数: 18

摘要

When an equimolar solution of various azoxybenzenes and SbCl5 in carbon tetrachloride were mixed, a 1: 1 complex immediately deposited as orange crystals in high yield. The thermal reaction of these complexes in inert solvents gives o-hydroxy-azobenzene selectively. On the contrary, other Lewis acids such as TiCl4, AlCl3, FeCl3 and ZnBr2 failed to give an isolatable complex with azoxybenzene, and their direct thermal reaction with ...