Chemistry Letters

Radiation-induced hydroxylation of thymine sensitized by nitro compounds in N2O-saturated aqueous solution.

T Wada, H Ide, S Nishimoto, T Kagiya

文献索引：Wada, Takeshi; Ide, Hiroshi; Nishimoto, Sei-ichi; Kagiya, Tsutomu Chemistry Letters, 1982 , p. 1041 - 1044

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被引用次数: 11

摘要

Hydroxylation of thymine (1) to give thymine glycol (3) is remarkably promoted by the addition of nitro compounds (2a–f) in the γ-radiolysis of the N 2 O-saturated aqueous solution, although overall decomposition of 1 is depressed to some extent. The G-value of 3, increases linearly with increasing the one-electron reduction potential of 2a-f.