3, 3-Diethoxypropyl-lithium: a masked lithium propanal homoenolate

J Barluenga, C Rubiera, JR Fernández…

文献索引：Barluenga, Jose; Rubiera, Covadonga; Fernandez, Jose R.; Yus, Miguel Journal of the Chemical Society, Chemical Communications, 1987 , # 6 p. 425 - 426

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被引用次数: 4

摘要

3, 3-Diethoxypropyl-lithium is prepared by lithiation of the corresponding chlorinated precursor with lithium naphthalenide at–78° C; the reaction of this masked propanal homoenolate with different electrophilic reagents [HO, DO,(PhCH) S, n-CHCHO, PhCHO, n- CHCHO, PhCH [[double bond, length half m-dash]] NPh] leads to the corresponding mono- and bi-fu