Tetrahedron letters

Photolysis of 3-nitrophenyl azide: Trapping the reactive intermediates

TY Liang, GB Schuster

文献索引：Liang, Tsuei-Yun; Schuster, Gary B. Tetrahedron Letters, 1986 , vol. 27, # 29 p. 3325 - 3328

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被引用次数: 8

摘要

... J. Am. Chem. Soc., 106 (1984), p. 5228. 6); T.-Y. Liang, GB Schuster; J. Am. Chem. ... 7); Irradiation through a K 2 Cr 2 O 7 filter to low conversion (ca. 40%) insures that azide 1 is the primary light absorber. 4: 1 H NMR: δ in ppm (CDCl 3 ) 1.07 (6H, t; J=7 Hz), 2.71 (UH, q; J=7 Hz), 4.51 (1H, b), 7.12 (1H, dd; J=8 and 2 Hz), 7.25 (1H, t; J=8 Hz), 7.50 (1H, dd; J=8 and 2 Hz), 7.71 (1H, t; J=2 Hz); IR: ν 1530 and 1320 cm −1 ; MS: m/e 209 (M+, C 10 H 15 H 3 O 2 ). ...