Journal of the American Chemical Society

Organolanthanide-catalyzed intra-and intermolecular tandem CN and CC bond-forming processes of aminodialkenes, aminodialkynes, aminoalkeneynes, and …

Y Li, TJ Marks

文献索引：Li, Yanwu; Marks, Tobin J. Journal of the American Chemical Society, 1998 , vol. 120, # 8 p. 1757 - 1771

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被引用次数: 241

摘要

This contribution describes catalytic tandem CN and CC bond-forming reactions involving the intramolecular hydroamination/bicyclization and intermolecular hydroamination/ cyclization of olefins and alkynes using the organolanthanide complexes Cp'2LnCH (SiMe3) 2 and Me2SiCp''2LnCH (SiMe3) 2 (Cp'= η5-Me5C5; Cp''= η5-Me4C5; Ln= lanthanide) as precatalysts. In the case of the intramolecular processes, substrates of the structures RC⋮ ...