Reaction of 1-bromo-3-chloropropane with tellur and dimethyltelluride in the system of hydrazine hydrate-alkali

…, IM Korotaeva, DS Totyashinova, NA Korchevin

文献索引：Russavskaya; Levanova; Sukhomazova; Grabelnykh; Elaev; Klyba; Zhanchipova; Albanov; Korotaeva; Totyashinova; Korchevin Russian Journal of General Chemistry, 2006 , vol. 76, # 5 p. 726 - 729

全文：HTML全文

被引用次数: 9

摘要

Abstract A synthesis of oligomeric substance of thiocol type, the poly (trimethyleneditelluride) , from 1-bromo-3-chloropropane and elemental tellurium is performed using a hydrazine hydrate-alkali system. Reductive splitting of the tellurocol followed by alkylation with methyl iodide give rise to preparation of bis (methyltelluro) propane, which was synthesized also from dimethyltelluride and 1, 3-dihalopropanes using the N 2 H 4· H 2 O/KOH system. ...