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Tetrahedron

Diethoxymethylphosphonites and phosphinates. Intermediates for thesynthesis of α, β-and X aminoalkylphosphonous acids

JG Dingwalla, J Ehrenfreund, RG Hall

文献索引:Dingwall, J. G.; Ehrenfreund, J.; Hall, R. G. Tetrahedron, 1989 , vol. 45, # 12 p. 3787 - 3808

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被引用次数: 83

摘要

New Building blocks for the synthesis of functional alkyl phosphonous acids are described. Diethoxymethylphosphonites andphosphinates are readily prepared and undergo reactions typical ofphosphites and phosphonates. The products are stable to chemicaltransformations, readily handled and purified, and easilytransformed to the phosphonous acids.