Immobilized triazine-type dehydrocondensing reagents for carboxamide formation: ROMP-Trz-Cl and ROMP (OH)-Trz-Cl

…, S Kameyama, S Tani, M Kunishima

文献索引：Hioki, Kazuhito; Kameyama, Satomi; Tani, Shohei; Kunishima, Munetaka Chemical and Pharmaceutical Bulletin, 2007 , vol. 55, # 5 p. 825 - 828

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被引用次数: 11

摘要

New triazine-type dehydrocondensing reagents, such as ROMP-Trz-Cl and ROMP (OH)-Trz- Cl, were synthesized by a ring opening metathesis polymerization (ROMP) method, and these showed higher loading than conventional polymer-supported condensing reagents. These polymers effect the formation of amides in good yields by addition of a mixture of carboxylic acid, amine and NMM. ROMP (OH)-Trz-Cl, which contains hydroxyl groups in ...