Inversion of tertiary nitrogen in the nickel (II) complex of a tetradentate macrocyclic ligand containing three tertiary amine donors: X-ray structures of {Ni [3, 7, 11- …

…, EK Barefield, DG Van Derveer

文献索引：Foster, Keith A.; Barefield, E. Kent; Derveer, Donald G. Van Journal of the Chemical Society, Chemical Communications, 1986 , # 9 p. 680 - 681

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摘要

All three possible diastereoisomers of the title complex have been isolated although one of these apparently occurs only in a folded form with a fifth ligand occupying the basal position of the square pyramid; conversion between diastereoisomers requires additional ligands with the relative stabilities of the diastereoisomers depending upon the donor strength of the medium and, in water, upon the concentration of NaClO4.