Selective functionalisation of 1, 3-dienes via organosulphur intermediates
BT Golding, E Pombo-Villar, CJ Samuel
文献索引：Golding, Bernard T.; Pombo-Villar, Esteban; Samuel, Christopher J. Journal of the Chemical Society, Chemical Communications, 1985 , # 20 p. 1444 - 1445
The 1,2-adducts from 1,3-dienes and sulphenyl chlorides are shown to be useful intermediates by their conversions into a variety of functionalised alkenes. ... In connection with studies of the sesquiterpenes called turmerones, 1 we required methods for the oxidative function- alisation of 1,3-dienes, selectively at the terminal position. The synthetic applications of 1,3-dienes would be enhanced if just one of their double bonds could be transformed. We report ...
