Stereochemistry of the thermal decomposition of [2-(acyloxy) alkyl] triorganostannanes

B Jousseaume, N Noiret, M Pereyre, JM Frances…

文献索引：Jousseaume, Bernard; Noiret, Nicolas; Pereyre, Michel; Frances, Jean-Marc; Petraud, Michel Organometallics, 1992 , vol. 11, p. 3910 - 3914

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被引用次数: 15

摘要

Summy: The stereochemical study of the thermal de-composition of (2-(acyloxy) alkyi) triorganostannanes revealed an anti@-elimination of (acyioxy) triorganostannanes. The process is highly stereospecific and not pwtubd by the presence of a possible internal chelation favoring syn elimination. It corresponds to an open transition state. Kinetics of &elimination In cyclohexyl and norbornyi systems showed that the reaction is much more ...