Infrared Spectra and DFT Calculations for the Coinage Metal Hydrides MH,(H2) MH, MH2, M2H, M2H-, and (H2) CuHCu in Solid Argon, Neon, and Hydrogen

X Wang, L Andrews, L Manceron…

文献索引：Wang, Xuefeng; Andrews, Lester Journal of the American Chemical Society, 2003 , vol. 125, # 21 p. 6581 - 6587

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被引用次数: 45

摘要

Laser-ablated coinage metal atom reactions with H2 in excess argon, neon, and pure hydrogen are investigated through matrix infrared spectroscopy. The reaction products are identified by isotopic substitution (D2, HD, and H2+ D2) and verified by DFT calculations of vibrational fundamentals. The MH and (H2) MH molecules are observed for all group 11 metals, and the trihydride complex (H2) AuH3 is stabilized in pure hydrogen. The (H2) ...