Abstract The self-assembly of chiral depsipeptide dendrons 4, which contain a cyanuric acid building block at their focal point, with the homotritopic Hamilton receptor 1 is reported. The 1: 3 compositions of the resulting chiral supramolecular dendrimers, the association constants K n, and the cooperativity of binding expressed by Scatchard plots and the Hill coefficients n H was determined by NMR titration experiments. The most pronounced ...