Total synthesis of racemic and optically active sarkomycin

…, MW Wieczorek, J Baszczyk, WR Majzner

文献索引：Mikolajczyk, Marian; Zurawinski, Remigiusz; Kielbasinski, Piotr; Wieczorek, Michal W.; Blaszczyk, Jaroslaw; Majzner, Wieslaw R. Synthesis, 1997 , # 3 p. 356 - 365

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被引用次数: 2

摘要

" Institute of General Food Chemistry, Technical University of Lédi, PL-90-924 Lodi, Stefanowskiego 4/10, Poland Received 10 December 1996 trans-3-Carboxy-2- dicthoxyphosphorylcyclopentanone (11), a key precursor of sarkomycin I, has been synthesized in the rhodium (II) acetate promoted cyclization of diethyl 1-diazo-2-oxohept-6- ene phosphonate (9), followed by transformation of the 3-vinyl moiety into the 3-carboxylic ...