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Journal of the American Oil Chemists' Society

Configurational purity of lesquerolic acid

PE Sonnet, D Hayes

文献索引:Sonnet, Philip E.; Hayes, Douglas Journal of the American Oil Chemists' Society, 1995 , vol. 72, # 9 p. 1069 - 1071

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被引用次数: 0

摘要

Abstract Conversion of the methyl ester of lesquerolic acid,(R)-14-hydroxy-Z-11-eicosenoic acid, to a carbamate with (S)-1-(1′-naphthyl) ethylisocyanate gave a single diastereomer. Comparisons of elution orders of the relevant diastereomers obtained from the racemic ester and from a sample of lesquerolic acid synthesized from ricinoleic acid,(R)-12-hydroxy-Z-9- octadecenoic acid, were consistent with the original assignment of (R)-configuration for ...