Studies in Organic Sulfur Compounds. V. 1 Synthesis of 21-Thiolacetates of Adrenal Cortical Hormones

C Djerassi, AL Nussbaum

文献索引：Djerassi; Nussbaum Journal of the American Chemical Society, 1953 , vol. 75, p. 3700,3703

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被引用次数: 9

摘要

In order to make available for biological experiments cortical hormone analogs in which the 21-hydroxyl function is replaced by sulfur, the 21-thiolacetate analogs of desoxycorticosterone, Reichstein's substance Sand cortisone as well as those of a number of intermediates and model compounds were prepared. The methods of preparation involved either decomposition of the appropriate diazoketone with thioacetic acid or ...