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Synthesis

4, 4, 6-Trimethyl-1, 3, 2-dioxaborinane: A Practical Reagent for Palladium-Catalyzed Borylation of Aryl Halides

M Murata, T Oda, S Watanabe, Y Masuda

文献索引:Murata, Miki; Oda, Takeshi; Watanabe, Shinji; Masuda, Yuzuru Synthesis, 2007 , # 3 p. 351 - 354

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被引用次数: 16

摘要

Abstract The palladium-catalyzed borylation of aryl iodides with 4, 4, 6-trimethyl-1, 3, 2- dioxaborinane is described. The mild reaction conditions employed allow for aryl iodides with a wide variety of functional groups to be tolerated. The products of this borylation were coupled with aryl halides to give biaryls in good yields.