The Journal of organic chemistry

Synthesis of polysubstituted furans based on a stepwise Sonogashira coupling of (Z)-3-iodoalk-2-en-1-ols with terminal propargylic alcohols and subsequent Au (I)-or …

X Zhang, Z Lu, C Fu, S Ma

文献索引：Zhang, Xiaobing; Lu, Zhan; Fu, Chunling; Ma, Shengming Organic and Biomolecular Chemistry, 2009 , vol. 7, # 16 p. 3258 - 3263

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被引用次数: 47

摘要

Recently, we have developed highly regio-and stereoselective carbometalation of 2- alkynols and 2, 3-allenols. The organometallacyclic intermediates may be trapped with I2 to afford 3-iodoalk-2-en-1-ols. These 3-iodoalk-2-en-1-ols may readily undergo the