Total synthesis of amphilectane-type diterpenoids:(±)-8, 15-diisocyano-11 (20)-amphilectene

…, M Llinas-Brunet, RM Oballa

文献索引：Piers; Llinas-Brunet; Oballa Canadian Journal of Chemistry, 1993 , vol. 71, # 9 p. 1484 - 1494

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被引用次数: 12

摘要

A total synthesis of the structurally novel, antimicrobial diterpenoid (±)-8, 15-diisocyano-11 (20)-amphilectene (2) is described. Alkylation of 2-methoxycarbonyl-3-methylcyclohexanone (13) with (E)-1-(tert-butyldimethylsiloxy)-6-iodo-3-(trimethylstannyl)-2-hexene (14) provided,