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Chemical Communications

Gold (I)-catalyzed intramolecular hydroamination of unactivated CC bonds with alkylammonium salts

CF Bender, RA Widenhoefer

文献索引:Bender, Christopher F.; Widenhoefer, Ross A. Chemical Communications, 2008 , # 24 p. 2741 - 2743

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被引用次数: 35

摘要

Concurrent with the recent proliferation of gold(I)-catalyzed organic transformations 10,11 has been the development of a number of gold(I)-catalyzed protocols for the hydroamination of unactivated C C bonds with carboxamide derivatives 12 and sulfonamides. 13 However, extension of gold(I)-catalyzed alkene hydroamination to include alkylamines has not been demonstrated, presumably due to non-productive displacement of the alkene by the amine and/or ...