Preparation of phenolic compounds through catalyst-free ipso-hydroxylation of arylboronic acids

…, M du Plessis, JH van Tonder, BCB Bezuidenhoudt

文献索引：Gohain, Mukut; Du Plessis, Maretha; Van Tonder, Johannes H.; Bezuidenhoudt, Barend C.B. Tetrahedron Letters, 2014 , vol. 55, # 13 p. 2082 - 2084

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被引用次数: 11

摘要

Abstract A novel method for the preparation of phenolic compounds through ipso- hydroxylation of the corresponding widely available arylboronic acid precursors is described. Through application of a novel PEG400-H 2 O 2 reactant system, a variety of substituted phenols and other aromatic analogues have been prepared in excellent yields at room temperature in the absence of any catalyst.