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Chemistry Letters

Stereospecific synthesis of (.+-.)-. BETA.-santalol.

K Sato, O Miyamoto, S Inoue, K Honda

文献索引:Sato, Kikumasa; Miyamoto, Osamu; Inoue, Seiichi; Honda, Kiyoshi Chemistry Letters, 1981 , p. 1183 - 1184

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被引用次数: 18

摘要

A stereospecific synthesis of 1-acetoxy-5-bromo-2-methyl-2-cis-pentene in 4 steps starting from 3-formyl-5, 6-dihydro-2H-pyran, dimer of acrolein, followed by alkylation of 2- ethoxycarbonyl-3-methylbicyclo [2.2. 1] hept-2-ene with the bromide furnished a facile synthesis of (±)-β-santalol.