Journal of Organometallic Chemistry

Beiträge zur chemie des bors LX zur reaktion von borhalogeniden mit trimethyl-stannyldiphenylphosphin-metall-pentacarbonylen: …

H Nöth, SN Sze

文献索引：Noeth, H.; Sze, S. N. Journal of Organometallic Chemistry, 1972 , vol. 43, p. 249 - 256

全文：HTML全文

被引用次数: 5

摘要

Abstract The stannylphosphine-metal pentacarbonyls (CO) 5 M· PPh 2 SnMe 3 (M= Cr, Mo, W) methylate BCl 3 and yield the monochloro compounds (CO) 5 M· PPh 2 SnMe 2 Cl. However, up to two of the methyl groups are replaced during the reaction with BBr 3 in benzene solution, the products being (CO) 5 M· PPh 2 SnMe 2 Br and (CO) 5 M· PPh 2 SnMeBr 2.