Reactivity of the perhaloalkanes CF2X2 (X= Cl, Br) with nucleophiles. 6. Coexistence of carbene and radical processes initiated by single electron transfer

I Rico, D Cantacuzene…

文献索引：Rixo, I.; Cantacuzene, D.; Wakselman, C. Journal of Organic Chemistry, 1983 , vol. 48, # 12 p. 1979 - 1982

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被引用次数: 46

摘要

Conclusion The capabilities of the CAMEO program have been extended to include electrophilic and nucleophilic processes involving organosilicon intermediates. The unique reactivity and directing ability of silyl groups required modification to several parts of the program, including the perception of acidities, electrophiles, nucleophiles, and carbonium ion stabilities. In addition, the stereochemical sophistication of the program has been ...