Electrochemical synthesis of diethyl fluoromethanephosphonate

…, BI Martynov, YD Smirnov, FM Semchenko

文献索引：Tomilov; Martynov; Smirnov; Semchenko Journal of Fluorine Chemistry, 1997 , vol. 82, # 1 p. 39 - 41

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被引用次数: 3

摘要

The electrochemical reduction of diethyl chlorofluoromethanephosphonate has been studied. It has been shown that, in mildly basic media (pH 7.5–8) of water-alcohol solutions, replacement of the chlorine of the starting compound by hydrogen occurs at lead, cadmium and zinc electrodes with high selectivity. The procedure affording diethyl fluoromethanephosphonate in a yield of 85%–90% has been elaborated.