Electron transfer sensitized photolysis of'onium salts

…, E Schmidt, N Serpone, DK Sharma

文献索引：DeVoe, R. J.; Sahyun, R. V.; Schmidt, Einhard; Serpone, N.; Sharma, D. K. Canadian Journal of Chemistry, 1988 , vol. 66, p. 319 - 324

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被引用次数: 74

摘要

We have studied the anthracene-sensitized photolyses of both diphenyliodonium and triphenylsulphonium salts in solution using both steady-state and laser flash photolysis techniques. Photoproducts, namely, phenylated anthracenes along with iodobenzene or diphenylsulphide, respectively, are obtained from both salts with quantum efficiencies of ca. 0.1 at 375 nm. We infer the intermediacy of diphenyliodo and triphenylsulphur radicals ...