Exploring Rhodium (I) Complexes [RhCl (COD)(PR3)](COD= 1, 5-Cyclooctadiene) as Catalysts for Nitrile Hydration Reactions in Water: The Aminophosphines Make …

E Tomás-Mendivil, R García-Álvarez, C Vidal…

文献索引：Tomas-Mendivil, Eder; Garcia-Alvarez, Rocio; Vidal, Cristian; Crochet, Pascale; Cadierno, Victorio ACS Catalysis, 2014 , vol. 4, # 6 p. 1901 - 1910

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被引用次数: 12

摘要

Several rhodium (I) complexes,[RhCl (COD)(PR3)], containing potentially cooperative phosphine ligands, have been synthesized and evaluated as catalysts for the selective hydration of organonitriles into amides in water. Among the different phosphines screened, those of general composition P (NR2) 3 led to the best results. In particular, complex [RhCl (COD){P (NMe2) 3}] was able to promote the selective hydration of a large range of nitriles ...