Tetrahedron

Rhodium-carbenoid mediated OH insertion reactions. OH insertion vs. H-abstraction and effect of catalyst

…, DJ Miller, CJ Moody, ERHB Sie, JJ Kulagowski

文献索引：Cox, Geoffrey G.; Miller, David J.; Moody, Christopher J.; Sie, Eric-Robert H. B.; Kulagowski, Janusz J. Tetrahedron, 1994 , vol. 50, # 10 p. 3195 - 3212

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被引用次数: 66

摘要

The synthesis and rhodium mediated OH insertion reactions of a wide range of diazo compounds are described. The rate at which the diazo compounds decompose in the presence of 2-propanol and the rhodium catalyst is strongly dependent on the electron withdrawing group (s) attached to the diazo carbon, with diazophosphonates being the least reactive. Insertion into the OH bond of methanol, t-butanol and phenols was also ...