Tetrahedron

Synthesis of the racemic forms of carbon–carbon double bond locked analogues of strobilurins which are characterized by a 2-arylcyclopropane ring cis-substituted at …

A Carpita, A Ribecai, R Rossi, P Stabile

文献索引：Carpita, Adriano; Ribecai, Arianna; Rossi, Renzo; Stabile, Paolo Tetrahedron, 2002 , vol. 58, # 19 p. 3673 - 3680

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被引用次数: 17

摘要

The racemic forms of three new carbon–carbon double bond locked analogues of strobilurins, which are characterized by a 2-arylcyclopropane ring cis-substituted at C-1 by the methyl (E)-3-methoxypropenoate unit, have been synthesized according to a strategy which involves the palladium-catalyzed synthesis of methyl (E)-3-methoxy-2-[(Z)-2-(aryl) ethenyl] propenoates and their stereospecific cyclopropanation.